effect of alkyl substituents on the hydrogen catalytic osmylation of cis and trans 2-cyclohexene-cyclohexanol
نویسندگان
چکیده
catalytic osmylation of cis and trans 2-cyclohexene-cyclohexanol (1a) and (1b) are carried out in the presence of n-methyl morpholine-n-oxide. under the same conditions, only the cis isomer reacted, leading to triol (3). the steric hindrance of the equatorial oh group probably prevents the trans isomer from entering into such reaction. triol (3) was also obtained from the reduction of the diol-ketone (4).
منابع مشابه
Effect of Alkyl Substituents on the Hydrogen Catalytic Osmylation of Cis and Trans 2-Cyclohexene-Cyclohexanol
Catalytic osmylation of cis and trans 2-cyclohexene-cyclohexanol (1a) and (1b) are carried out in the presence of N-methyl morpholine-N-oxide. Under the same conditions, only the cis isomer reacted, leading to triol (3). The steric hindrance of the equatorial OH group probably prevents the trans isomer from entering into such reaction. Triol (3) was also obtained from the reduction of the d...
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عنوان ژورنال:
iranian journal of chemistry and chemical engineering (ijcce)ناشر: iranian institute of research and development in chemical industries (irdci)-acecr
ISSN 1021-9986
دوره 14
شماره 2 2014
میزبانی شده توسط پلتفرم ابری doprax.com
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